GREASE = BASE OIL(S) + THICKENER(S) + ADDITIVES
a. Base oils
- Minerals: derived through distillation of the petroleum without synthesis - Synthetics: derived from chemical synthesis reactions
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Hydrocarboned (PIB, PAO…) |
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Oxygenated (esters, glycols, ethers…) |
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Miscellaneous |
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Halogenated (PFPE…) |
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Silica-containing (silicones) |
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etc. |
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Mixtures of different base metals are often made, which may or may not belong to the same category.
The properties that differentiate the base oils are mainly:
- intrinsic lubricity - solvent properties - temperature stability - behavior at low temperature (liquid / solid transition) - viscosity index (translates the viscosity variation according to the temperature) - ignition point - biodegradability
b. Thickener
Thickeners are used to obtain the desired viscosity (consistency), thus making it a firm paste that does not flow. It also contributes to the fundamental properties of the grease: lubrication, anti-wear, extreme pressure, etc.
The thickener can be formed "in situ" by a chemical reaction or be added in the form of an "external" thickener.
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In situ: |
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Soaps: |
Lithium (Li) |
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Calcium (Ca) |
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Lithium / Calcium |
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"Lithium complex" |
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Polyureas |
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Calcium sulfonates or "Calcium complexes" |
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External: |
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Mineral pulverulents (silica gels, bentones, metallic powders…) |
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Organic pulverulents (teflon, organic loads…) |
c. Additives
Compounds of mineral or organic origin and various functionalities:
- anti-friction - anti-wear - extreme pressure - adhesion - preservative agents (stabilization of the oil) - anti-corrosion for lubricated metal surfaces (iron, copper, aluminum…) - water repellent agents - colorants, …
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